2-Fluoro-N-o-tolylbenzamide
نویسندگان
چکیده
In the title compound, C(14)H(12)FNO, the ortho-F atom and corresponding H atom on the fluoro-benzene ring are disordered over two positions with occupancies of 0.856 (4) and 0.144 (4). The amide unit is planar with a maximum deviation of 0.0057 (16) Å and the amide plane makes dihedral angles of 38.27 (11)° with the fluoro-benzene ring plane and 37.53 (10)° with the tolyl ring. The two benzene rings are inclined at an angle of 4.17 (15)°. In the crystal structure, chains form along b through N-H⋯O hydrogen bonds augmented by C-H⋯π inter-actions. Additional inter-molecular C-H⋯O and C-H⋯F hydrogen bonds further stabilize the structure, forming layers in the ac plane.
منابع مشابه
4-Chloro-N-o-tolylbenzamide
In the mol-ecule of the title compound, C(14)H(12)ClNO, the two benzene rings are close to coplanar [dihedral angle = 7.85 (4)°]. The amide N-C=O plane makes dihedral angles of 34.04 (4) and 39.90 (3)°, respectively, with the 4-chloro- and 2-methyl-phenyl rings. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains.
متن کامل2,4-Dichloro-N-o-tolylbenzamide
In the title compound, C(14)H(11)Cl(2)NO, the central C-C(O)-N-C amide unit makes dihedral angles of 68.71 (11) and 54.92 (12)°, respectively, with the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 16.25 (17)°. In the crystal, N-H⋯O hydrogen bonds link mol-ecules into zigzag chains propagating in [001]. C-H⋯Cl contacts link these chains and additional C-H⋯O contacts g...
متن کامل2-Methyl-N-o-tolylbenzamide
In the title compound, C(15)H(15)NO, the C-N-C(O)-C amide unit is planar (r.m.s. deviation = 0.003 Å) and subtends dihedral angles of 44.71 (5) and 43.33 (5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94 (7)° to one another. The ortho-methyl groups of the two tolyl rings are anti to one another. In the crystal structure, N-H⋯O hydrogen bonds augmented by C-H⋯π inter-act...
متن کامل2,4-Dichloro-N-p-tolylbenzamide
In the title compound, C(14)H(11)Cl(2)NO, the C-N-C(=O)-C amide unit is almost planar (r.m.s. deviation = 0.0317 Å) and subtends dihedral angles of 65.93 (6) and 29.45 (7)°, respectively, to the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 37.92 (6)° to one another. In the crystal structure, N-H⋯O hydrogen bonds link the mol-ecules into chains along b. Additional wea...
متن کامل4-Chloro-N-m-tolylbenzamide
In the title compound, C(14)H(12)ClNO, the dihedral angle between the two aromatic rings is 11.29 (15)°. The crystal packing is stabilized by N-H⋯O hydrogen bonds linking the mol-ecules into chains running along the c axis.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2008